In situ observation of rapid reactions in nanoscale Ni-Al multilayer foils using synchrotron radiation

被引:40
作者
Fadenberger, Konrad [1 ,2 ]
Gunduz, Ibrahim Emre [2 ]
Tsotsos, Chrysostomos [2 ]
Kokonou, Maria [2 ]
Gravani, Styliani [2 ]
Brandstetter, Stefan [3 ]
Bergamaschi, Anna [3 ]
Schmitt, Bernd [3 ]
Mayrhofer, Paul H. [1 ]
Doumanidis, Charalabos C. [2 ]
Rebholz, Claus [2 ]
机构
[1] Montan Univ Leoben, Dept Phys Met & Mat Testing, A-8700 Leoben, Austria
[2] Univ Cyprus, Dept Mech & Mfg Engn, CY-1678 Nicosia, Cyprus
[3] Paul Scherrer Inst, CH-5232 Villigen, Switzerland
关键词
SELF-PROPAGATING REACTIONS; COMBUSTION SYNTHESIS; EXOTHERMIC REACTIONS; TEMPERATURE; DETECTOR; SYSTEMS;
D O I
10.1063/1.3485673
中图分类号
O59 [应用物理学];
学科分类号
摘要
The observation of rapid reactions in nanoscale multilayers present challenges that require sophisticated analysis methods. We present high-resolution in situ x-ray diffraction analysis of reactions in nanoscale foils of Ni0.9V0.1-Al using the Mythen II solid-state microstrip detector system at the Material Science beamline of the Swiss Light Source Synchrotron at Paul Scherrer Institute in Villigen, Switzerland. The results reveal the temperature evolution corresponding to the rapid formation of NiAl intermetallic phase, vanadium segregation and formation of stresses during cooling, determined at high temporal (0.125 ms) and angular (0.004 degrees) resolution over a full angular range of 120 degrees. (C) 2010 American Institute of Physics. [doi:10.1063/1.3485673]
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页数:3
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