Transfer hydrogenation of imines catalyzed by a nickel(0)/NHC complex

被引:98
作者
Kuhl, S [1 ]
Schneider, R [1 ]
Fort, Y [1 ]
机构
[1] Fac Sci, CNRS, UMR 7565, UHP, F-54506 Vandoeuvre Les Nancy, France
关键词
D O I
10.1021/om034046n
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Transfer hydrogenation of imines to the corresponding amines by Et2CHONa catalyzed by the mono-coordinate Ni(0)/N-heterocyclic carbene species Ni(0)/IMes has been studied. Using this catalyst, a variety of aldimines and ketimines were reduced in good to excellent yields under mild conditions.
引用
收藏
页码:4184 / 4186
页数:3
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