Transfer hydrogenation of imines catalyzed by a nickel(0)/NHC complex

被引:98
作者
Kuhl, S [1 ]
Schneider, R [1 ]
Fort, Y [1 ]
机构
[1] Fac Sci, CNRS, UMR 7565, UHP, F-54506 Vandoeuvre Les Nancy, France
关键词
D O I
10.1021/om034046n
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Transfer hydrogenation of imines to the corresponding amines by Et2CHONa catalyzed by the mono-coordinate Ni(0)/N-heterocyclic carbene species Ni(0)/IMes has been studied. Using this catalyst, a variety of aldimines and ketimines were reduced in good to excellent yields under mild conditions.
引用
收藏
页码:4184 / 4186
页数:3
相关论文
共 42 条
  • [31] 2-Q
  • [32] Increased ring closing metathesis activity of ruthenium-based olefin metathesis catalysts coordinated with imidazolin-2-ylidene ligands
    Scholl, M
    Trnka, TM
    Morgan, JP
    Grubbs, RH
    [J]. TETRAHEDRON LETTERS, 1999, 40 (12) : 2247 - 2250
  • [33] New chiral phosphorus ligands for enantioselective hydrogenation
    Tang, WJ
    Zhang, XM
    [J]. CHEMICAL REVIEWS, 2003, 103 (08) : 3029 - 3069
  • [34] Asymmetric transfer hydrogenation of imines
    Uematsu, N
    Fujii, A
    Hashiguchi, S
    Ikariya, T
    Noyori, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (20) : 4916 - 4917
  • [35] Synthesis, characterization, and catalytic activity of N-heterocyclic carbene (NHC) palladacycle complexes
    Viciu, MS
    Kelly, RA
    Stevens, ED
    Naud, F
    Studer, M
    Nolan, SP
    [J]. ORGANIC LETTERS, 2003, 5 (09) : 1479 - 1482
  • [36] RUTHENIUM-CATALYZED TRANSFER HYDROGENATION OF IMINES BY PROPAN-2-OL
    WANG, GZ
    BACKVALL, JE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (14) : 980 - 982
  • [37] UNIMOLECULAR REACTIONS OF IONIZED ALKANES
    WENDELBOE, JF
    BOWEN, RD
    WILLIAMS, DH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) : 2333 - 2339
  • [38] Weskamp T, 1998, ANGEW CHEM INT EDIT, V37, P2490, DOI 10.1002/(SICI)1521-3773(19981002)37:18<2490::AID-ANIE2490>3.0.CO
  • [39] 2-X
  • [40] Efficient Sonogashira, reactions of aryl bromides with alkynylsilanes catalyzed by a palladium/imidazolium salt system
    Yang, CL
    Nolan, SP
    [J]. ORGANOMETALLICS, 2002, 21 (06) : 1020 - 1022