Mesoporous Mn2O3 and Mn3O4 with crystalline walls

被引:152
作者
Jiao, Feng
Harrison, Andrew
Hill, Adrian H.
Bruce, Peter G. [1 ]
机构
[1] Univ St Andrews, Sch Chem & EaStChem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Edinburgh, Sch Chem & EaStChem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
D O I
10.1002/adma.200700336
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ordered mesoporous; Mn2O3 and I Mn3O4 with crystalline walls (see figure) have been successfully synthesized. Mesoporous Mn2O3 was converted to Mn3O4 in a reducing atmosphere without destroying the ordered mesostructure, which gives the first example of mesoporous Mn3O4 or any reduced mesoporous manganese oxide, something that is unlikely to be achieved by direct template synthesis.
引用
收藏
页码:4063 / +
页数:5
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