Three-Dimensionally Arrayed and Mutually Connected 1.2-nm Nanopores for High-Performance Electric Double Layer Capacitor

被引:258
作者
Itoi, Hiroyuki [1 ]
Nishihara, Hirotomo [1 ]
Kogure, Taichi [1 ]
Kyotani, Takashi [1 ]
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan
关键词
ORDERED MICROPOROUS CARBONS; ELECTROCHEMICAL CAPACITORS; PROPYLENE CARBONATE; NANOTUBE ELECTRODES; ZEOLITE; TEMPLATE;
D O I
10.1021/ja108315p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Zeolite-templated carbon is a promising candidate as an electrode material for constructing an electric double layer capacitor with both high-power and high-energy densities, due to its three-dimensionally arrayed and mutually connected 1.2-nm nanopores. This carbon exhibits both very high gravimetric (140-190 F g(-1)) and volumetric (75-83 F cm(-3)) capacitances in an organic electrolyte solution. Moreover, such a high capacitance can be well retained even at a very high current up to 20 A g(-1). This extraordinary high performance is attributed to the unique pore structure.
引用
收藏
页码:1165 / 1167
页数:3
相关论文
共 22 条
  • [1] An KH, 2001, ADV FUNCT MATER, V11, P387, DOI 10.1002/1616-3028(200110)11:5<387::AID-ADFM387>3.0.CO
  • [2] 2-G
  • [3] The large electrochemical capacitance of microporous doped carbon obtained by using a zeolite template
    Ania, Conchi O.
    Khomenko, Volodymyr
    Raymundo-Pinero, Encarnacion
    Parra, Jose B.
    Beguin, Francois
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (11) : 1828 - 1836
  • [4] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377
  • [5] Chmiola J, 2006, SCIENCE, V313, P1760, DOI 10.1126/science/1132195
  • [6] Desolvation of ions in subnanometer pores and its effect on capacitance and double-layer theory
    Chmiola, John
    Largeot, Celine
    Taberna, Pierre-Louis
    Simon, Patrice
    Gogotsi, Yury
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (18) : 3392 - 3395
  • [7] Shape-engineerable and highly densely packed single-walled carbon nanotubes and their application as super-capacitor electrodes
    Futaba, Don N.
    Hata, Kenji
    Yamada, Takeo
    Hiraoka, Tatsuki
    Hayamizu, Yuhei
    Kakudate, Yozo
    Tanaike, Osamu
    Hatori, Hiroaki
    Yumura, Motoo
    Iijima, Sumio
    [J]. NATURE MATERIALS, 2006, 5 (12) : 987 - 994
  • [8] An easy method for the synthesis of ordered microporous carbons by the template technique
    Hou, PX
    Yamazaki, T
    Orikasa, H
    Kyotani, T
    [J]. CARBON, 2005, 43 (12) : 2624 - 2627
  • [9] Capacitance properties of ordered porous carbon materials prepared by a templating procedure
    Jurewicz, K
    Vix-Guterl, C
    Frackowiak, E
    Saadallah, S
    Reda, A
    Parmentier, J
    Patarin, J
    Béguin, F
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2004, 65 (2-3) : 287 - 293
  • [10] Principles and applications of electrochemical capacitors
    Kötz, R
    Carlen, M
    [J]. ELECTROCHIMICA ACTA, 2000, 45 (15-16) : 2483 - 2498