A General pH-Responsive Supramolecular Nanovalve Based on Mesoporous Organosilica Hollow Nanospheres

被引：74

作者：

Guo, Wanping ^{[1
]}

Wang, Jing ^{[1
]}

Lee, Sang-Joon ^{[1
]}

Dong, Fuping ^{[1
]}

Park, Sung Soo ^{[1
]}

Ha, Chang-Sik ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Polymer Sci & Engn, Pusan 609735, South Korea

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 29期

关键词：

delivery systems; mesoporous materials; pH responsive; rotaxanes; supramolecular chemistry; CONTROLLED-RELEASE; MOLECULAR MACHINES; SILICA SUPPORTS; IMMOBILIZATION; NANOCONTAINERS; CYCLODEXTRIN;

D O I：

10.1002/chem.201000980

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Smart release on demand: A general pH-responsive supramolecular nano-valve operating in aqueous media has been designed by using mesoporous organosilica hollow nanospheres as nanocontainers (see picture). The nanovalve is capable of storing guest molecules within the hollow core and mesopore shell and releasing them on demand by acid/base triggering of the capping molecule, demonstrating a delicate vehicle for controlled release. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH &Co. KGaA, Weinheim.

引用

页码：8641 / 8646

页数：6

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