Highly selective cross-metathesis with phenyl vinyl sulphone using the 'second generation' Grubbs' catalyst

被引:64
作者
Grela, K [1 ]
Bieniek, M [1 ]
机构
[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
关键词
carbene complex; olefin metathesis; sulfone; ruthenium; homogenous catalysis;
D O I
10.1016/S0040-4039(01)01269-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A cross-metathesis reaction was achieved between functionalised terminal olefins and phenyl vinyl sulfone by using the commercially available ruthenium catalyst Ile. The cross-metathesis products were isolated in moderate to good yield with excellent (E)-stereoselectivity. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6425 / 6428
页数:4
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