Diamination of conjugated dienes and trienes catalyzed by N-heterocyclic carbene-Pd(0) complexes

被引:53
作者
Xu, Liang [1 ]
Du, Haifeng [1 ]
Shi, Yian [1 ]
机构
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
关键词
D O I
10.1021/jo0709394
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This paper describes a diamination process using di-t-butyldiaziridinone as nitrogen source and N-heterocyclic carbene-Pd(0) complex as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities.
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页码:7038 / 7041
页数:4
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