Advanced in situ characterization methods applied to carbonaceous materials

被引：71

作者：

Novák, P ^{[1
]}

Goers, D ^{[1
]}

Hardwick, L ^{[1
]}

Holzapfel, M ^{[1
]}

Scheifele, W ^{[1
]}

Ufhiel, J ^{[1
]}

Würsig, A ^{[1
]}

机构：

[1] Paul Scherrer Inst, Electrochem Lab, CH-5232 Villigen, Switzerland

来源：

JOURNAL OF POWER SOURCES | 2005年 / 146卷 / 1-2期

关键词：

lithium-ion battery; graphite electrode; in situ X-ray diffraction; in situ Raman mapping; in situ mass spectrometry; in situ infrared spectroscopy;

D O I：

10.1016/j.jpowsour.2005.03.129

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper is an overview of the progress recently achieved in our laboratory in the development and application of four in situ methods; namely X-ray diffraction (both synchrotron-based and standard), Raman microscopy, differential electrochemical mass spectrometry (DEMS), and infrared spectroscopy. We show representative results on graphite electrodes for each method as an illustration, in particular (i) the influence of the lithium intercalation and graphite exfoliation on the shift of the (0 0 2)-reflection of graphite, (ii) Raman single point and mapping measurements of graphite surface, (iii) gas evolution during solid electrolyte interphase (SEI) formation on graphite electrodes, and (iv) the development of infrared spectra during the SEI formation in gamma-butyrolactone based electrolytes. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：15 / 20

页数：6

共 31 条

[1] A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on ethylene carbonate dimethyl carbonate mixtures [J].

Aurbach, D ;

Markovsky, B ;

Shechter, A ;

EinEli, Y ;

Cohen, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (12) :3809-3820

[2] Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries [J].

Aurbach, D .

JOURNAL OF POWER SOURCES, 2000, 89 (02) :206-218

[3] New insights into the interactions between electrode materials and electrolyte solutions for advanced nonaqueous batteries [J].

Aurbach, D ;

Markovsky, B ;

Levi, MD ;

Levi, E ;

Schechter, A ;

Moshkovich, M ;

Cohen, Y .

JOURNAL OF POWER SOURCES, 1999, 81 :95-111

[4] Electrode-solution interactions in Li-ion batteries: a short summary and new insights [J].

Aurbach, D .

JOURNAL OF POWER SOURCES, 2003, 119 :497-503

[5] In situ AFM imaging of surface phenomena on composite graphite electrodes during lithium insertion [J].

Aurbach, D ;

Koltypin, M ;

Teller, H .

LANGMUIR, 2002, 18 (23) :9000-9009

[6] Structural studies of the stage III lithium-graphite intercalation compound [J].

Billaud, D ;

Henry, FX .

SOLID STATE COMMUNICATIONS, 2002, 124 (08) :299-304

[7] Revisited structures of dense and dilute stage II lithium-graphite intercalation compounds [J].

Billaud, D ;

Henry, FX ;

Lelaurain, M ;

Willmann, P .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1996, 57 (6-8) :775-781

[8] Properties of large Li ion cells using a nickel based mixed oxide [J].

Broussely, A ;

Blanchard, P ;

Biensan, P ;

Planchat, JP ;

Nechev, K ;

Staniewicz, RJ .

JOURNAL OF POWER SOURCES, 2003, 119 :859-864

[9]

BUQA H, 2003, ITE LETT BATTERIES N, V4, P38

[10] Raman spectroscopic and structural studies of heat-treated graphites for lithium-ion batteries [J].

Goers, D ;

Buqa, H ;

Hardwick, L ;

Wursig, A ;

Novák, P .

IONICS, 2003, 9 (3-4) :258-265

← 1 2 3 4 →