Miniemulsion polymerization

被引:381
作者
Schork, FJ [1 ]
Luo, YW
Smulders, W
Russum, JP
Butté, A
Fontenot, K
机构
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
[2] Zhejiang Univ, Coll Mat & Chem Engn, State Key Lab Polymer React Engn, Hangzhou 310027, Peoples R China
[3] ETH Honggerberg, Inst Chem & Bioengn, ETH Zurich, Prof M Morbidelli Grp, CH-8093 Zurich, Switzerland
[4] Eastman Chem Co, Kingsport, TN 37662 USA
来源
POLYMER PARTICLES | 2005年 / 175卷
关键词
miniemulsion; polymerization; emulsion; free radical; colloid;
D O I
10.1007/b100115
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The subject of miniemulsion polymerization is reviewed. The approach taken is one that combines a review of the technology with historical and tutorial aspects. Rather than developing an absolutely exhaustive review, a tutorial approach has been taken, emphasizing the critical features and advantages of miniemulsion polymerization. In keeping with this tutorial approach, a discussion of conventional emulsion polymerization is included in order to be able to compare and contrast miniemulsion polymerization and conventional emulsion polymerization later in the review. Areas where miniemulsion polymerization has been adopted commercially, or where it is likely to be adopted are highlighted.
引用
收藏
页码:129 / 255
页数:127
相关论文
共 363 条
[101]  
2-9
[102]   Structural characterization of nitroxide-terminated poly(n-butyl acrylate) prepared in bulk and miniemulsion polymerizations [J].
Farcet, C ;
Belleney, J ;
Charleux, B ;
Pirri, R .
MACROMOLECULES, 2002, 35 (13) :4912-4918
[103]   Poly(n-butyl acrylate) homopolymer and poly[n-butyl acrylate-b-(n-butyl acrylate-co-styrene)] block copolymer prepared via nitroxide-mediated living/controlled radical polymerization in miniemulsion [J].
Farcet, C ;
Charleux, B ;
Pirri, R .
MACROMOLECULES, 2001, 34 (12) :3823-3826
[104]   Mechanistic aspects of nitroxide-mediated controlled radical polymerization of styrene in miniemulsion, using a water-soluble radical initiator [J].
Farcet, C ;
Lansalot, M ;
Charleux, B ;
Pirri, R ;
Vairon, JP .
MACROMOLECULES, 2000, 33 (23) :8559-8570
[105]   COAGULATIVE NUCLEATION AND PARTICLE-SIZE DISTRIBUTIONS IN EMULSION POLYMERIZATION [J].
FEENEY, PJ ;
NAPPER, DH ;
GILBERT, RG .
MACROMOLECULES, 1984, 17 (12) :2520-2529
[106]   The persistent radical effect in ''living'' radical polymerization [J].
Fischer, H .
MACROMOLECULES, 1997, 30 (19) :5666-5672
[107]  
Fischer H, 1999, J POLYM SCI POL CHEM, V37, P1885, DOI 10.1002/(SICI)1099-0518(19990701)37:13<1885::AID-POLA1>3.0.CO
[108]  
2-1
[109]  
Fitch R. M., 1973, British Polymer Journal, V5, P467, DOI 10.1002/pi.4980050606
[110]  
Flory P J., PRINCIPLES POLYM CHE