Cyclopentadienyl-NHC Iron Complexes for Solvent-Free Catalytic Hydrosilylation of Aldehydes and Ketones

被引：93

作者：

Bezier, David ^{[1
]}

Jiang, Fan ^{[1
]}

Roisnel, Thierry ^{[1
]}

Sortais, Jean-Baptiste ^{[1
]}

Darcel, Christophe ^{[1
]}

机构：

[1] Univ Rennes 1 Sci Chim Rennes Catalysis & Organom, CNRS, Ctr Diffractometrie X, F-35042 Rennes, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 09期

关键词：

Iron; Homogeneous catalysis; Hydrosilylation; Aldehydes; Ketones; N-HETEROCYCLIC CARBENE; RING-OPENING POLYMERIZATION; INTRAMOLECULAR CYCLOTRIMERIZATION; MONO-CARBENE; LIGANDS; HETEROATOM; BEARING; TRIYNES; HALIDES; FE(II);

D O I：

10.1002/ejic.201100762

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Seven cyclopentadienylNHC piano-stool iron complexes were prepared and studied in the catalytic hydrosilylation of aldehydes and ketones under visible light irradiation. A significant acceleration of the rate was observed when the reactions were carried out under solvent-free conditions. Single-crystal X-ray structural analyses were performed for complexes 5 and 7.

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收藏

页码：1333 / 1337

页数：5

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