Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters

被引：267

作者：

Coventry, DN

Batsanov, AS

Goeta, AE

Howard, JAK

Marder, TB

Perutz, RN

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 16期

关键词：

D O I：

10.1039/b501778e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The selectivity of the iridium boryl complex-catalysed reaction of pyrene and perylene with B-2(pin)(2) (pin = OCMe2CMe2O) has been employed in the synthesis of D-2h-symmetry pyrene-2,7-( Bpin)(2) and D-4h-symmetry perylene-2,5,8,11-(Bpin)(4) providing direct borylation of positions which are otherwise difficult to derivatise.

引用

页码：2172 / 2174

页数：3

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