Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system

被引:39
作者
Feuerstein, M [1 ]
Laurenti, D [1 ]
Doucet, H [1 ]
Santelli, M [1 ]
机构
[1] Fac Sci St Jerome, Synth Organ Lab, CNRS, UMR 6009, F-13397 Marseille 20, France
关键词
D O I
10.1039/b007860n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)-cyclopentane/[PdCl(C3H5)](2) system catalyses allylic amination in good yields with a very high substrate/catalyst ratio; a turnover number of 680 000 and a turnover frequency of 8125 h(-1) can be obtained for the addition of dipropylamine to allyl acetate in the presence of this catalyst.
引用
收藏
页码:43 / 44
页数:2
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