Characteristics and potential applications of a novel forward osmosis hollow fiber membrane

被引:232
作者
Chou, Shuren [1 ,2 ]
Shi, Lei [2 ]
Wang, Rong [1 ,2 ]
Tang, Chuyang Y. [1 ,2 ]
Qiu, Changquan [1 ]
Fane, Anthony G. [1 ,2 ]
机构
[1] Nanyang Technol Univ, Sch Civil & Environm Engn, Singapore 639798, Singapore
[2] Nanyang Technol Univ, Singapore Membrane Technol Ctr, Singapore 639798, Singapore
关键词
Forward osmosis (FO); Hollow fiber; Thin film composite membrane (TFC); Internal concentration polarization (ICP); Seawater desalination; INTERNAL CONCENTRATION POLARIZATION; PRESSURE-RETARDED OSMOSIS; CONCENTRATED BRINES; PERFORMANCE; RHEOLOGY; ENERGY; FLUX;
D O I
10.1016/j.desal.2010.06.027
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
There has been a resurgence of interest in forward osmosis (FO) as a potential means of desalination, dewatering and in pressure retarded osmosis, which Sidney Loeb was advocating over 3 decades ago. This paper describes the characteristics and potential applications of a newly developed FO hollow fiber membrane, which was fabricated by interfacial polymerization on the inner surface of a polyethersulfone (PES) hollow fiber. This FO membrane presents excellent intrinsic separation properties, with a water flux of 42.6 L/m(2) h using 0.5 M NaCl as the draw solution and DI water as the feed with the active layer facing the draw solution orientation at 23 degrees C. The corresponding ratio of salt flux to water flux was only 0.094 g/L, which is superior to all other FO membranes reported in the open literature. To evaluate different application scenarios, various NaCl solutions (500 ppm (8.6 mM), 1 wt.% (0.17 M) and 3.5 wt.% (0.59 M)) were used as the feed water to test the performance of the FO membrane. The membrane can achieve a water flux of 12.4 L/m(2) h with 3.5 wt.% NaCl solution as the feed and 2 M NaCl as the draw solution, suggesting it has good potential for seawater desalination. (c) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:365 / 372
页数:8
相关论文
共 23 条
[1]   Forward osmosis: Principles, applications, and recent developments [J].
Cath, Tzahi Y. ;
Childress, Amy E. ;
Elimelech, Menachem .
JOURNAL OF MEMBRANE SCIENCE, 2006, 281 (1-2) :70-87
[2]   Membrane fouling and process performance of forward osmosis membranes on activated sludge [J].
Cornelissen, E. R. ;
Harmsen, D. ;
de Korte, K. F. ;
Ruiken, C. J. ;
Qin, Jian-Jun ;
Oo, H. ;
Wessels, L. P. .
JOURNAL OF MEMBRANE SCIENCE, 2008, 319 (1-2) :158-168
[3]   Internal concentration polarization in forward osmosis: role of membrane orientation [J].
Gray, Gordon T. ;
McCutcheon, Jeffrey R. ;
Elimelech, Menachem .
DESALINATION, 2006, 197 (1-3) :1-8
[4]   Forward osmosis for concentration of anaerobic digester centrate [J].
Holloway, Ryan W. ;
Childress, Amy E. ;
Dennett, Keith E. ;
Cath, Tzahi Y. .
WATER RESEARCH, 2007, 41 (17) :4005-4014
[5]   Interfacially polymerized hydrophilic microporous thin film composite membranes on porous polypropylene hollow fibers and flat films [J].
Korikov, A. R. ;
Kosaraju, P. B. ;
Sirkar, K. K. .
JOURNAL OF MEMBRANE SCIENCE, 2006, 279 (1-2) :588-600
[6]   PRODUCTION OF ENERGY FROM CONCENTRATED BRINES BY PRESSURE-RETARDED OSMOSIS .2. EXPERIMENTAL RESULTS AND PROJECTED ENERGY COSTS [J].
LOEB, S ;
VANHESSEN, F ;
SHAHAF, D .
JOURNAL OF MEMBRANE SCIENCE, 1976, 1 (03) :249-269
[7]   Effect of porous support fabric on osmosis through a Loeb-Sourirajan type asymmetric membrane [J].
Loeb, S ;
Titelman, L ;
Korngold, E ;
Freiman, J .
JOURNAL OF MEMBRANE SCIENCE, 1997, 129 (02) :243-249
[8]   PRODUCTION OF ENERGY FROM CONCENTRATED BRINES BY PRESSURE-RETARDED OSMOSIS .1. PRELIMINARY TECHNICAL AND ECONOMIC CORRELATIONS [J].
LOEB, S .
JOURNAL OF MEMBRANE SCIENCE, 1976, 1 (01) :49-63
[9]   Influence of concentrative and dilutive internal concentration polarization on flux behavior in forward osmosis [J].
McCutcheon, Jeffrey R. ;
Elimelech, Menachem .
JOURNAL OF MEMBRANE SCIENCE, 2006, 284 (1-2) :237-247
[10]   Desalination by ammonia-carbon dioxide forward osmosis: Influence of draw and feed solution concentrations on process performance [J].
McCutcheon, Jeffrey R. ;
McGinnis, Robert L. ;
Elimelech, Menachern .
JOURNAL OF MEMBRANE SCIENCE, 2006, 278 (1-2) :114-123