Relativistic corrections to the energies of the EF, GK, and H(H)over-bar 1Σg states of the hydrogen molecule

被引：24

作者：

Wolniewicz, L ^{[1
]}

机构：

[1] Nicholas Copernicus Univ, Inst Phys, PL-87100 Torun, Poland

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 06期

关键词：

D O I：

10.1063/1.476852

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Relativistic corrections to the electronic energies are computed for the EF, GK, and H (H) over bar (1)Sigma(g) states of the hydrogen molecule in a wide range of internuclear distances. Term values for the J=0 levels are given for the EF state and for the outer well of the H (H) over bar state. A comparison with experiment shows that the adiabatic, relativistic theoretical H (H) over bar energies are too low by about 1 cm(-1). (C) 1998 American Institute of Physics.

引用

页码：2254 / 2256

页数：3

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