Synthetic applications of functionalized silyl anions: Aminosilyl anions as hydroxy anion equivalent

被引：35

作者：

Tamao, K ^{[1
]}

Kawachi, A ^{[1
]}

Tanaka, Y ^{[1
]}

Ohtani, H ^{[1
]}

Ito, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM,KYOTO 606,JAPAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 16期

关键词：

D O I：

10.1016/0040-4020(96)00212-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An (aminosilyl)lithium and the corresponding copper and magnesium reagents serve as a hydroxy anion equivalent through (1) allylic substitution, (2) addition to vinyloxirane, and (3) addition to acetylene, followed by oxidative cleavage of the silicon-carbon bonds. Highly regio- and stereoselective transformations have been achieved in all cases. (C) 1996 Elsevier Science Ltd.

引用

页码：5765 / 5772

页数：8

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