One-Pot Multistep Reactions Based on Thiolactones: Extending the Realm of Thiol-Ene Chemistry in Polymer Synthesis

被引：212

作者：

Espeel, Pieter ^{[1
]}

Goethals, Fabienne ^{[1
]}

Du Prez, Filip E. ^{[1
]}

机构：

[1] Univ Ghent, Dept Organ Chem, Polymer Chem Res Grp, B-9000 Ghent, Belgium

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 06期

关键词：

CLICK-CHEMISTRY;

D O I：

10.1021/ja1098098

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The in situ generation of thiols by nucleophilic ring-opening of a thiolactone with amines, followed by a UV-initiated radical thiol-ene reaction in a one-pot fashion, has been evaluated as an accelerated and versatile protocol for the synthesis of several types of polymeric architectures. After elaboration of a model amine-thiol-ene conjugation reaction, a number of routes based on readily available thiolactone-containing structures have been developed to successfully assemble functional, linear polymers and networks via a mild and facile radical photopolymerization process.

引用

页码：1678 / 1681

页数：4

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