Hybrid Polyoxometalates: Merging Organic and Inorganic Domains for Enhanced Catalysis and Energy Applications

被引：35

作者：

Berardi, Serena ^{[1
]}

Carraro, Mauro

Sartorel, Andrea

Modugno, Gloria

Bonchio, Marcella

机构：

[1] Univ Padua, ITM CNR, I-35131 Padua, Italy

来源：

ISRAEL JOURNAL OF CHEMISTRY | 2011年 / 51卷 / 02期

关键词：

C-C coupling; epoxidation; homogeneous catalysis; hybrid catalysis; ionic liquids; microwave-assisted reactions; polyoxometalates; CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENES; 30-PERCENT HYDROGEN-PEROXIDE; TEMPERATURE SUZUKI-MIYAURA; IONIC LIQUIDS; METAL-OXIDE; ARYL CHLORIDES; KEGGIN-TYPE; OLEFIN EPOXIDATION; SUBSTITUTED POLYOXOMETALATE;

D O I：

10.1002/ijch.201100018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organic inorganic hybrids based on polyoxometalate scaffolds(POMs) are a unique class of molecular metal-oxides featuring a composite surface, whereby the merging of complementary domains stimulates new functions and enhances performances. The interaction between the organic and inorganic components can be designed via covalent and/or non-covalent strategies, yielding novel molecular systems with key applications in catalysis and materials science. Selected examples of such a rewarding approach will be illustrated, including the synthesis of tailored POM-based catalysts, and their application in homogeneous systems and on electrocatalytic surfaces for water splitting and renewable energy production.

引用

页码：259 / 274

页数：16

共 199 条

[1] Enhancement of reaction rates by segmented fluid flow in capillary scale reactors [J].