Highly fluorescent self-coordinated phthalocyanine dimers

被引：129

作者：

Kameyama, K ^{[1
]}

Morisue, M ^{[1
]}

Satake, A ^{[1
]}

Kobuke, Y ^{[1
]}

机构：

[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma 6300192, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 30期

关键词：

aggregation; fluorescence; phthalocyanines; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200501199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Head-to-tail self-assembly of two imidazolylphthalocyaninatozinc(II) or -magnesium(II) units through mutual imidazole-metal interactions leads to strongly fluorescent dimers (see picture, ΦF = fluorescence quantum yield) that exhibit high association constants estimated at over 10 11 M 1 in toluene. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4763 / 4766

页数：4

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