Bubble visualization and electrolyte dependency of dissolving hydrogen in electrolyzed water using Solid-Polymer-Electrolyte

被引:32
作者
Tanaka, Y [1 ]
Kikuchi, K
Saihara, Y
Ogumi, Z
机构
[1] Home Appliances Co, Matsushita Elect Works Ltd, Ctr Res & Dev, Osaka 5718686, Japan
[2] Univ Shiga Prefecture, Dept Mat Sci, Shiga 5228533, Japan
[3] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Kyoto 6158510, Japan
关键词
bubble visualization; hydrogen dissolution; electrolyte solution; water electrolysis; solid-polymer-electrolyte;
D O I
10.1016/j.electacta.2005.01.062
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Solid-polymer-electrolyte electrolysis was performed in electrolyte solutions of different concentrations. The higher the electrolyte concentration, the higher the concentration of dissolved hydrogen as H-2 molecule. The concentration of dissolved hydrogen was high in the high electrolyte solutions only when current density was high. In an effort to clarify this finding, the electrolytic generated hydrogen bubble was visualized using a high speed camera. Numerous bubbles were formed under high current density, therefore, the degree of bubble coalescence increased. The bubble coalescence, however, was inhibited by addition of electrolytes. In the electrolyte solution, the hydrogen bubbles maintained the released bubble size. The high concentration of dissolved hydrogen was attributable to the bubble coalescence inhibited by the electrolyte. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5229 / 5236
页数:8
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