Processable donor-acceptor type electrochromes switching between multicolored and highly transmissive states towards single component RGB-based display devices

被引:43
作者
Balan, Abidin [1 ]
Baran, Derya [1 ]
Toppare, Levent [1 ]
机构
[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
关键词
HETEROJUNCTION SOLAR-CELLS; DESIGNING SYNTHETIC METALS; CONJUGATED POLYMERS; BAND-GAP; NEUTRAL STATE; GREEN POLYMER; PHOTOVOLTAIC DEVICES; CONCEPT WORK; ELECTRON; PERFORMANCE;
D O I
10.1039/c0jm01815e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Donor-acceptor (DA) type polymers, poly(2-alkyl-4-(thiophen-2-yl)-2H-benzo[1,2,3]triazole)s (PTBT-DAs), with alternating alkyl chain substitution were synthesized and characterized in terms of their electrochemical and optical properties. Spray processable polymers have multicolored states upon oxidation and showed ambipolar characteristics in which n-type doping allowed them to achieve a transparent state in a low working potential range. Reported electrochemical and spectral results showed that PTBT-DAs are great candidates for single component electrochromic display devices. In the context of low cost flexible display device technology, requirements for polymers showing multicolored and transmissive states can be fulfilled by PTBT-DAs.
引用
收藏
页码:9861 / 9866
页数:6
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