Reaction chemistry during self-propagating high-temperature synthesis (SHS) of H3BO3-ZrO2-Mg system

被引：15

作者：

Khanra, A. K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Met & Mat Engn, Kharagpur 721302, W Bengal, India

来源：

MATERIALS RESEARCH BULLETIN | 2007年 / 42卷 / 12期

关键词：

carbides; ceramics; electron microscopy; X-ray diffraction; defects;

D O I：

10.1016/j.materresbull.2007.01.016

中图分类号：

T [工业技术];

学科分类号：

08 [工学];

摘要：

In the present investigation, the ZrB2 powder is produced by SHS of mixture containing H3BO3, ZrO2 and Mg. The thermal analysis and XRD study reveal the reaction mechanism of ZrB2 formation by SHS process. Synthesis of H3BO3-Mg System results in formation Of Mg-3(BO3)(2) and MgB4 phases, whereas ZrO2 is partially reduced to ZrO3 and Zr during synthesis of ZrO2-Mg system. The reaction between elemental Zr and MgB4 results in ZrB2 formation. The particle size of ZrB2 is found to decrease with the addition of SHS diluent. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2224 / 2229

页数：6

共 10 条

[1]

Preparation and some properties of nanocrystalline ZrB2 powders [J].

Chen, LY ;

Gu, YL ;

Yang, ZH ;

Shi, L ;

Ma, JH ;

Qian, YT .

SCRIPTA MATERIALIA, 2004, 50 (07) :959-961

[2]

KINETICS OF THE COMBUSTION SYNTHESIS OF TIB2 [J].

HOLT, JB ;

KINGMAN, DD ;

BIANCHINI, GM .

MATERIALS SCIENCE AND ENGINEERING, 1985, 71 (1-2) :321-327

[3]

Effect of NaCl on the synthesis of TiB2 powder by a self-propagating high-temperature synthesis technique [J].

Khanra, AK ;

Pathak, LC ;

Mishra, SK ;

Godkhindi, MM .

MATERIALS LETTERS, 2004, 58 (05) :733-738

[4]

KHANRA AK, 2005, ADV APPL CERAM, V104, P1

[5]

LOGAN KV, 1984, CERAM ENG SCI P, V5, P712

[6]

FABRICATION OF NEW ZIRCONIUM BORIDE CERAMICS [J].

LOW, IM ;

MCPHERSON, R .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1989, 8 (11) :1281-1283

[7]

Preparation of TiB2 and ZrB2 influence of a mechanochemical treatment on the borothermic reduction of titania and zirconia [J].

Millet, P ;

Hwang, T .

JOURNAL OF MATERIALS SCIENCE, 1996, 31 (02) :351-355

[8]

Properties of titanium and zirconium diborides obtained by self-propagated high-temperature synthesis [J].

Radev, DD ;

Marinov, M .

JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 244 (1-2) :48-51

[9]

WEIMIN W, 2002, J MATER PROCESS TECH, V128, P162, DOI DOI 10.1016/S0924-0136(02)00444-2

[10]

PREPARATION OF ZIRCONIUM BORIDE POWDER [J].

ZHAO, H ;

HE, Y ;

JIN, ZZ .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (09) :2534-2536

← 1 →