Copper clusters built on bulky amidinate ligands:: spin delocalization via superexchange rather than direct metal-metal bonding

被引：30

作者：

Jiang, X ^{[1
]}

Bollinger, JC

Baik, MH

Lee, D

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Sch Informat, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 08期

关键词：

D O I：

10.1039/b412152j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Entry into a new class of tetra- and dicopper clusters was assisted by a fine steric tuning of bulky amidinate ligands that provide spin-delocalizing superexchange pathways in class III mixed-valence clusters, the properties of which are best understood without invoking metal-metal bonding.

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页码：1043 / 1045

页数：3

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