A dithioxo-bishydroxylaminomolybdenum complex as sulfur and nitrogen transfer reagent.: Synthesis of thioureas from isonitriles

被引：7

作者：

Byrne, JJ

Vallée, Y

机构：

[1] CNRS, LEDSS, F-38041 Grenoble, France

[2] Univ Grenoble 1, F-38041 Grenoble, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 03期

关键词：

D O I：

10.1016/S0040-4039(98)02418-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cis-dithioxo-bis((N,N-diethyl)hydroxylamido(1-)-O,N)molydenum(VI) reacts with isonitriles to give the corresponding N,N-diethylthioureas. A mechanism is proposed for this S,N-transfer reaction. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：489 / 490

页数：2

共 12 条

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