Redox control of light-induced platinum-cluster-to-iron charge transfer in a bis(ferrocenylethynyl)-substituted hexanuclear platinum derivative

被引：44

作者：

Albinati, A

de Biani, FF

Leoni, P

Marchetti, L

Pasquali, M

Rizzato, S

Zanello, P

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

[2] Univ Siena, Dipartimento Chim, I-53100 Siena, Italy

[3] Univ Milan, DCSSI, I-20133 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 35期

关键词：

alkynyl ligands; cluster compounds; electron transfer; ferrocenes; platinum;

D O I：

10.1002/anie.200501714

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Give and take: Compound 1 (see structure: purple Pt, red Fe, green P, blue O; Fc = [η-C5H 5)Fe(η-C5H4)]) is prepared in good yields by the Cul-catalyzed coupling of two equivalents of ethynylferrocene with the hexanuclear cluster [Pt6(μ-PtBu2)4(CO) 4Cl2]. Electrochemical and spectroelectrochemical data show the presence of photoelectrochemically triggered electron transfer from the {Pt6} core to the peripheral ferrocenyl subunits. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5701 / 5705

页数：5

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