Novel chiral calix[4]arenes by direct asymmetric epoxidation reaction

被引：21

作者：

Bonini, Carlo ^{[1
]}

Chiummiento, Lucia ^{[1
]}

Funicello, Maria ^{[1
]}

Lopardo, Maria Teresa ^{[1
]}

Lupattelli, Paolo ^{[1
]}

Laurita, Alessandro ^{[1
]}

Cornia, Andrea ^{[2
,3
]}

机构：

[1] Univ Basilicata, Dipartimento Chim, I-85100 Potenza, Italy

[2] Univ Modena & Reggio Emilia, Dipartimento Chim, I-41100 Modena, Italy

[3] INSTM, I-41100 Modena, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 11期

关键词：

D O I：

10.1021/jo800301m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report the first asymmetric synthesis of trans optically active H C(2) 1,3-bisarylepoxide of calix[4]arene in excellent chemical yield and >99% ee, and its enantiospecific conversion to the corresponding bis-dioxolane.

引用

页码：4233 / 4236

页数：4

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