Synthesis and X-ray structure of a complex containing two (η3-allyl)MoII units bridged by MoVIO42- and exhibiting an unusual type of aggregation

被引:10
作者
Borgmann, C [1 ]
Limberg, C [1 ]
Zsolnai, L [1 ]
机构
[1] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1039/a805154b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of the [Mo(eta(3)-C3H4Me)(bipy)(CO)(2)(Me2CO)](+) cation with an aqueous MoO42- solution enabled the first structural characterisation of an (eta(3)-allyl)MoO complex, which aggregates to a dimer showing Mo-O ... H-C contacts in the solid state.
引用
收藏
页码:2729 / 2730
页数:2
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