Phase-field model of solidification of a binary alloy

被引:82
作者
Bi, ZQ [1 ]
Sekerka, RF [1 ]
机构
[1] Carnegie Mellon Univ, Dept Phys, Pittsburgh, PA 15213 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0378-4371(98)00364-1
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We develop a rather general thermodynamically consistent phase-field model for solidification of a binary alloy, based on an entropy functional that contains squared gradient terms in the energy density, the composition and the phase-field variable. By assuming positive local entropy production, we derive generalized phase-field equations for an alloy, including cross terms that connect thermal and compositional driving forces to energy and solute fluxes. We explore this model in detail for a regular solution and show that four existing models can be recovered as special cases. We also use it to develop a new phase-field model for an alloy in which an explicit phase-field variable is absent. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:95 / 106
页数:12
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