Effect of preparation conditions on the properties of highly reduced Rh/TiO2 (anatase and rutile) catalysts

被引：4

作者：

Holgado, MJ ^{[1
]}

Iñigo, AC ^{[1
]}

Rives, V ^{[1
]}

机构：

[1] Univ Salamanca, Dept Quim Inorgan, E-37008 Salamanca, Spain

来源：

APPLIED CATALYSIS A-GENERAL | 1998年 / 175卷 / 1-2期

关键词：

D O I：

10.1016/S0926-860X(98)00211-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rh/TiO2 catalysts have been prepared under different experimental conditions (namely, crystallographic phase of the support, Rh loading, incorporation method, etc.) and reduced at 773 K. Hydrogenolysis of n-butane has been used as a reaction test to characterize these catalysts. The reaction parameters (activation energy and frequency factor) have been determined and the change in selectivity to methane, ethane and propane has been studied following the Kempling-Anderson formalism. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：33 / 41

页数：9

共 41 条

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