Hierarchical mesoporous carbon/silica nanocomposites from phenyl-bridged organosilane

被引:76
作者
Pang, JB
John, VT
Loy, DA
Yang, ZZ
Lu, YF [1 ]
机构
[1] Tulane Univ, Dept Chem & Biomol Engn, New Orleans, LA 70118 USA
[2] Los Alamos Natl Lab, Polymers & Coating Grp, Los Alamos, NM 87545 USA
[3] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
关键词
D O I
10.1002/adma.200400873
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mesoporous carbon/silica nanocomposites (see Figure) have been synthesized by carbonization of an ordered mesostructured phenylene/silica hybrid with both meso- and molecular-scale ordering. The carbon/silica nanocomposite exhibits an unique pore wall containing carbon and silica components. Removal of the silica results in the formation of mesoporous carbon that could potentially be used for hydrogen storage.
引用
收藏
页码:704 / +
页数:5
相关论文
共 28 条
[21]  
Stein A, 2000, ADV MATER, V12, P1403, DOI 10.1002/1521-4095(200010)12:19<1403::AID-ADMA1403>3.0.CO
[22]  
2-X
[23]   Advances in microporous and mesoporous solids - Highlights of recent progress [J].
Stein, A .
ADVANCED MATERIALS, 2003, 15 (10) :763-775
[24]   Synthesis of periodic mesoporous ethylenesilica under acidic conditions [J].
Wang, WH ;
Xie, SH ;
Zhou, WZ ;
Sayari, A .
CHEMISTRY OF MATERIALS, 2004, 16 (09) :1756-1762
[25]   Synthesis of periodic mesoporous phenylenesilica under acidic conditions with novel molecular order in the pore walls [J].
Wang, WH ;
Zhou, WZ ;
Sayari, A .
CHEMISTRY OF MATERIALS, 2003, 15 (26) :4886-4889
[26]   On the hydrothermal stability of mesoporous aluminosilicate MCM-48 materials [J].
Xia, YD ;
Mokaya, R .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (29) :6954-6960
[27]   Sulfuric acid-functionalized mesoporous benzene-silica with a molecular-scale periodicity in the walls [J].
Yang, QH ;
Kapoor, MP ;
Inagaki, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (33) :9694-9695
[28]   A condensable amphiphile with a cleavable tail as a "lizard" template for the sol-gel synthesis of functionalized mesoporous silica [J].
Zhang, QM ;
Ariga, K ;
Okabe, A ;
Aida, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (04) :988-989