The synthesis of tris(perfluoroalkyl)phosphines

被引：55

作者：

Murphy-Jolly, MB ^{[1
]}

Lewis, LC ^{[1
]}

Caffyn, AJM ^{[1
]}

机构：

[1] Univ W Indies, Dept Chem, St Augustine, Trinidad Tobago

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 35期

关键词：

D O I：

10.1039/b507752d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris(perfluoroalkyl) phosphines, of interest as tunable alternatives to the carbon monoxide ligand, can be synthesised by the nucleophile mediated reaction of perfluoroalkyltrimethylsilanes with triphenylphosphite; the method can be extended to diphosphines.

引用

页码：4479 / 4480

页数：2

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