A catalytic reaction inside a single-walled carbon nanotube

被引：158

作者：

Shiozawa, Hidetsugu ^{[1
]}

Pichler, Thomas ^{[1
]}

Grueneis, Alexander ^{[1
]}

Pfeiffer, Rudolf ^{[2
]}

Kuzmany, Hans ^{[2
]}

Liu, Zheng ^{[3
]}

Suenaga, Kazu ^{[3
]}

Kataura, Hiromichi ^{[4
]}

机构：

[1] IFW Dresden, D-01171 Dresden, Germany

[2] Univ Vienna, Inst Matphys, A-1090 Vienna, Austria

[3] AIST, Res Ctr Adv Carbon Mat, Tsukuba, Ibaraki 3058565, Japan

[4] AIST, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058562, Japan

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 08期

关键词：

D O I：

10.1002/adma.200701466

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A catalytic reaction inside a single-walled carbon nanotube is demonstrated by using encapsulated ferrocene molecules as precursors. A combined spectroscopic an microscopic study unravels the mechanism of catalytic inner tube growth. This confined process provides for the controlled iron growing of double-walled carbon nanotubes and represents a new route for materials design.

引用

收藏

页码：1443 / +

页数：8

相关论文

共 26 条

[1] Thermal decomposition of ferrocene as a method for production of single-walled carbon nanotubes without additional carbon sources [J].

Barreiro, Amelia ;

Hampel, Silke ;

Rummeli, Mark H. ;

Kramberger, Christian ;

Gruneis, Alexander ;

Biedermann, Kati ;

Leonhardt, Albrecht ;

Gemming, Thomas ;

Buchner, Bernd ;

Bachtold, Adrian ;

Pichler, Thomas .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (42) :20973-20977

[2] CARBIDE PHASES ON IRON-BASED FISCHER-TROPSCH SYNTHESIS CATALYSTS .1. CHARACTERIZATION STUDIES [J].

BUTT, JB .

CATALYSIS LETTERS, 1990, 7 (1-4) :61-81

[3] PHOTOELECTRON-SPECTRA OF METALLOCENES [J].

CAULETTI, C ;

GREEN, JC ;

KELLY, MR ;

POWELL, P ;

VANTILBORG, J ;

ROBBINS, J ;

SMART, J .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1980, 19 (04) :327-353

[4]

DWYER DJ, 1984, APPL SURF SCI, V19, P14

[5] Formation of small-diameter carbon nanotubes from PTCDA arranged inside the single-wall carbon nanotubes [J].

Fujita, Y ;

Bandow, S ;

Iijima, S .

CHEMICAL PHYSICS LETTERS, 2005, 413 (4-6) :410-414

[6] Tuning the electrical conductivity of nanotube-encapsulated metallocene wires [J].

García-Suárez, VM ;

Ferrer, J ;

Lambert, CJ .

PHYSICAL REVIEW LETTERS, 2006, 96 (10)

[7] Ferrocene-filled single-walled carbon nanotubes [J].

Guan, LH ;

Shi, ZJ ;

Li, MX ;

Gu, ZN .

CARBON, 2005, 43 (13) :2780-2785

[8] Direct observation of Tomonaga-Luttinger-liquid state in carbon nanotubes at low temperatures [J].

Ishii, H ;

Kataura, H ;

Shiozawa, H ;

Yoshioka, H ;

Otsubo, H ;

Takayama, Y ;

Miyahara, T ;

Suzuki, S ;

Achiba, Y ;

Nakatake, M ;

Narimura, T ;

Higashiguchi, M ;

Shimada, K ;

Namatame, H ;

Taniguchi, M .

NATURE, 2003, 426 (6966) :540-544

[9] Optical properties of fullerene and non-fullerene peapods [J].

Kataura, H ;

Maniwa, Y ;

Abe, M ;

Fujiwara, A ;

Kodama, T ;

Kikuchi, K ;

Imahori, H ;

Misaki, Y ;

Suzuki, S ;

Achiba, Y .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2002, 74 (03) :349-354

[10] Transition from one-dimensional to three-dimensional behavior induced by lithium doping in single wall carbon nanotubes [J].

Larciprete, R ;

Petaccia, L ;

Lizzit, S ;

Goldoni, A .

PHYSICAL REVIEW B, 2005, 71 (11)