A polyaniline-intercalated layered manganese oxide nanocomposite prepared by an inorganic/organic interface reaction and its high electrochemical performance for Li storage

被引：122

作者：

Wang, Yong-Gang ^{[1
,2
]}

Wu, Wen ^{[1
,2
]}

Cheng, Liang ^{[1
,2
]}

He, Ping ^{[1
,2
]}

Wang, Cong-Xiao ^{[1
,2
]}

Xia, Yong-Yao ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

ADVANCED MATERIALS | 2008年 / 20卷 / 11期

关键词：

D O I：

10.1002/adma.200701708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polyaniline is intercalated into layered manganese oxide in situ, at an aqueous/organic interface. The prepared polymer intercalated manganese oxide has several novel characteristics - a swelled layered structure, a uniform mesoporous structure, a typical nanosize, and a high surface area, resulting in a high electrochemical performance for Li storage.

引用

收藏

页码：2166 / +

页数：6

相关论文

共 29 条

[21] A new redox host for intercalative polymerization:: Insertion of polyaniline into α-RuCl3 [J].

Wang, L ;

Brazis, P ;

Rocci, M ;

Kannewurf, CR ;

Kanatzidis, MG .

CHEMISTRY OF MATERIALS, 1998, 10 (11) :3298-+

[22] α-RuCl3/polymer nanocomposites:: The first group of intercalative nanocomposites with transition metal halides [J].

Wang, L ;

Rocci-Lane, M ;

Brazis, P ;

Kannewurf, CR ;

Kim, YI ;

Lee, W ;

Choy, JH ;

Kanatzidis, MG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) :6629-6640

[23] Synthesis of a Li-Mn-oxide with disordered layer stacking through flocculation of exfoliated MnO2 nanosheets, and its electrochemical properties [J].

Wang, LZ ;

Takada, K ;

Kajiyama, A ;

Onoda, M ;

Michiue, Y ;

Zhang, LQ ;

Watanabe, M ;

Sasaki, T .

CHEMISTRY OF MATERIALS, 2003, 15 (23) :4508-4514

[24] Ordered whiskerlike polyaniline grown on the surface of mesoporous carbon and its electrochemical capacitance performance [J].

Wang, Yong-Gang ;

Li, Hui-Qiao ;

Xia, Yong-Yao .

ADVANCED MATERIALS, 2006, 18 (19) :2619-+

[25]

WU GG, 1995, J AM CHEM SOC, V117, P9229

[26] Structural characterization of self-assembled MnO2 nanosheets from birnessite manganese oxide single crystals [J].

Yang, XJ ;

Makita, Y ;

Liu, ZH ;

Sakane, K ;

Ooi, K .

CHEMISTRY OF MATERIALS, 2004, 16 (26) :5581-5588

[27] Synthesis of monodisperse nanocrystals of manganese oxides [J].

Yin, M ;

O'Brien, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (34) :10180-10181

[28] A self-ordered, crystalline-glass, mesoporous nanocomposite for use as a lithium-based storage device with both high power and high energy densities [J].

Zhou, HS ;

Li, DL ;

Hibino, M ;

Honma, I .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (05) :797-802

[29] Synthesis of MnO2 nanoparticles confined in ordered mesoporous carbon using a sonochemical method [J].

Zhu, SM ;

Zhou, HA ;

Hibino, M ;

Honma, I ;

Ichihara, M .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (03) :381-386