A XRD and TEM study on the transformation of amorphous calcium phosphate in the presence of magnesium

被引:110
作者
Abbona, F [1 ]
Baronnet, A [1 ]
机构
[1] CRMCC, CNRS, F-13218 MARSEILLE 9, FRANCE
关键词
D O I
10.1016/0022-0248(96)00156-X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The evolution of the amorphous calcium phosphate (ACP), precipitated at 25 degrees C from solutions of concentration [Ca] = [P] = 5 mM at pH = 7.94, was followed at fixed time intervals by combined X-ray, electron diffraction and TEM imaging. The same runs were carried out in the presence of magnesium ions (C = 1 mM). Only one kind of amorphous compound was observed (ACP1), which seems to change directly into apatite (HAP) without crystalline intermediate. Edge dislocations and grain boundaries were found by HRTEM analysis in HAP. The effects of magnesium on conversion of ACP into HAP and on the crystal structure and habit of HAP are interpreted in terms of incorporation and surface adsorption.
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页码:98 / 105
页数:8
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