Supermolecular building blocks (SBBs) and crystal design: 12-connected open frameworks based on a molecular cubohemioctahedron

被引:292
作者
Cairns, Amy J. [1 ]
Perman, Jason A. [1 ]
Wojtas, Lukasz [1 ]
Kravtsov, Victor Ch. [2 ]
Alkordi, Mohamed H. [1 ]
Eddaoudi, Mohamed [1 ]
Zaworotko, Michael J. [1 ]
机构
[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA
[2] Moldavian Acad Sci, MD-2028 Kishinev, Moldova
关键词
D O I
10.1021/ja078060t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cubchemioctahedral supermolecular building blocks, SBBS, of formula [M-6(bdc)(12)](12-) (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid tetracarboxylalo ligands in such a manner that 12-connected fcv nets with nanoscale features are generated. 3,5-H(4)ATC, L1, facilitates a structure with Ni that exhibits cavities with > 2 nm maximum dimensions, whereas H(4)BIPA-TC, L2, forms a net with Co or Ni that exhibits cavities with > 3 nm maximum dimensions.
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收藏
页码:1560 / +
页数:3
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