Supermolecular building blocks (SBBs) and crystal design: 12-connected open frameworks based on a molecular cubohemioctahedron

被引：292

作者：

Cairns, Amy J. ^{[1
]}

Perman, Jason A. ^{[1
]}

Wojtas, Lukasz ^{[1
]}

Kravtsov, Victor Ch. ^{[2
]}

Alkordi, Mohamed H. ^{[1
]}

Eddaoudi, Mohamed ^{[1
]}

Zaworotko, Michael J. ^{[1
]}

机构：

[1] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[2] Moldavian Acad Sci, MD-2028 Kishinev, Moldova

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 05期

关键词：

D O I：

10.1021/ja078060t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cubchemioctahedral supermolecular building blocks, SBBS, of formula [M-6(bdc)(12)](12-) (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid tetracarboxylalo ligands in such a manner that 12-connected fcv nets with nanoscale features are generated. 3,5-H(4)ATC, L1, facilitates a structure with Ni that exhibits cavities with > 2 nm maximum dimensions, whereas H(4)BIPA-TC, L2, forms a net with Co or Ni that exhibits cavities with > 3 nm maximum dimensions.

引用

页码：1560 / +

页数：3

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