Selective Removal of N-Heterocyclic Aromatic Contaminants from Fuels by Lewis Acidic Metal-Organic Frameworks

被引：164

作者：

Maes, Michael ^{[1
]}

Trekels, Maarten ^{[2
,3
]}

Boulhout, Mohammed ^{[4
]}

Schouteden, Stijn ^{[1
]}

Vermoortele, Frederik ^{[1
]}

Alaerts, Luc ^{[1
]}

Heurtaux, Daniela ^{[5
]}

Seo, You-Kyong ^{[6
]}

Hwang, Young Kyu ^{[6
]}

Chang, Jong-San ^{[6
]}

Beurroies, Isabelle ^{[4
]}

Denoyel, Renaud ^{[4
]}

Temst, Kristiaan ^{[2
,3
]}

Vantomme, Andre ^{[2
,3
]}

Horcajada, Patricia ^{[5
]}

Serre, Christian ^{[5
]}

De Vos, Dirk E. ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium

[2] Katholieke Univ Leuven, Inst Kern Stralingsfys, B-3001 Louvain, Belgium

[3] Katholieke Univ Leuven, INPAC, B-3001 Louvain, Belgium

[4] Univ Aix Marseille 1 3, CNRS, Lab Chim Provence, MATDIV Grp,Ctr St Jerome,UMR 6264, F-13397 Marseille 20, France

[5] Univ Versailles St Quentin En Yvelines, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France

[6] Res Inst Technol KRICT, Catalysis Ctr Mol Engn, Taejon 305600, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 18期

关键词：

adsorption; fuels; Lewis acidity; microporous materials; purification; TRANSPORTATION FUELS; MICROWAVE SYNTHESIS; NITROGEN-COMPOUNDS; ADSORPTION; SEPARATION; DESULFURIZATION; CATALYST; ETHYLBENZENE; TEMPERATURE; ZEOLITES;

D O I：

10.1002/anie.201100050

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bring in the cleaner! Metal-organic frameworks (MOFs) are able to separate nitrogen and sulfur contaminants from fuel, which may lead to the production of cleaner fuels (see picture; ppmw=parts per million by weight). The separation ability is shown to originate from the Lewis acidity of the metal sites in the MOFs. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4210 / 4214

页数：5

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