A single-strand polymer of hexacoordinated zinc(II) phosphodiester complex

被引：15

作者：

Angeloff, A ^{[1
]}

Daran, JC ^{[1
]}

Bernadou, J ^{[1
]}

Meunier, B ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 624卷 / 1-2期

关键词：

zinc; bis(p-nitrophenyl)phosphate; single-strand polymer;

D O I：

10.1016/S0022-328X(00)00892-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the title compound 2, catena-poly{aqua(dimethylformamide-O)bis{mu-[bis(p-nitrophenyl)phosphato]}zinc(II) mono(dimethylformamide)}, consists of linear polymers in which adjacent Zn2+ cations are joined by the oxygen atoms of two bidentate bridging phosphate diester ligands 1. The metal shows an octahedral coordination geometry with the zinc connected to six O atoms, four belonging to four different surrounding phosphate groups, one to a water molecule and one to a DMF molecule. Each single-strand is built-up from Zn octahedrons having alternate configuration A or A. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：58 / 62

页数：5

共 19 条

[1] SIR97:: a new tool for crystal structure determination and refinement
Altomare, A
Burla, MC
Camalli, M
Cascarano, GL
Giacovazzo, C
Guagliardi, A
Moliterni, AGG
Polidori, G
Spagna, R
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 115 - 119
[2] Angeloff A, 2000, EUR J INORG CHEM, P1985
[3] ANGELOFF A, 1999, THESIS TOULOUSE U
[4] Carboxy and phosphate esters cleavage with mono- and dinuclear zinc(II) macrocyclic complexes in aqueous solution, crystal structure of [Zn(2)L1(mu-PP)(2)(MeOH)(2)](ClO4)(2) (L1=[30]aneN(6)O(4), PP- equals diphenyl phosphate)
Bazzicalupi, C
Bencini, A
Bianchi, A
Fusi, V
Giorgi, C
Paoletti, P
Valtancoli, B
Zanchi, D
[J]. INORGANIC CHEMISTRY, 1997, 36 (13) : 2784 - 2790
[5] One- and two-metal ion catalysis of the hydrolysis of adenosine 3'-alkyl phosphate esters. Models for one- and two-metal ion catalysis of RNA hydrolysis
Bruice, TC
Tsubouchi, A
Dempcy, RO
Olson, LP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (41) : 9867 - 9875
[6] Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations
[7] CRYSTAL-STRUCTURE AND PHYSICOCHEMICAL PROPERTIES OF BIS(MU-METHYLPHENYL-PHOSPHINATO) ZINC(II).DIOXANE [ZN[OP(CH3)(C6H5)O]2]N.NC4H8O2
CINI, R
ORIOLI, P
SABAT, M
GILLMAN, HD
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1982, 59 (02): : 225 - 230
[8] Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI [DOI 10.1107/S0021889899006020, 10.1107/S0021889899006020]
[9] CRYSTAL STRUCTURES OF MONOCLINIC AND ORTHORHOMBIC FORMS OF ZINC(2) N-BUTYLPHENYLPHOSPHINATE POLYMER
GIORDANO, F
RANDACCI.L
RIPAMONT.A
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 : 1057 - &
[10] METAL-ION PROMOTED PHOSPHATE ESTER HYDROLYSIS - INTRAMOLECULAR ATTACK OF COORDINATED HYDROXIDE ION
HENDRY, P
SARGESON, AM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) : 2521 - 2527

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