A single-strand polymer of hexacoordinated zinc(II) phosphodiester complex

被引：15

作者：

Angeloff, A ^{[1
]}

Daran, JC ^{[1
]}

Bernadou, J ^{[1
]}

Meunier, B ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 624卷 / 1-2期

关键词：

zinc; bis(p-nitrophenyl)phosphate; single-strand polymer;

D O I：

10.1016/S0022-328X(00)00892-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the title compound 2, catena-poly{aqua(dimethylformamide-O)bis{mu-[bis(p-nitrophenyl)phosphato]}zinc(II) mono(dimethylformamide)}, consists of linear polymers in which adjacent Zn2+ cations are joined by the oxygen atoms of two bidentate bridging phosphate diester ligands 1. The metal shows an octahedral coordination geometry with the zinc connected to six O atoms, four belonging to four different surrounding phosphate groups, one to a water molecule and one to a DMF molecule. Each single-strand is built-up from Zn octahedrons having alternate configuration A or A. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：58 / 62

页数：5

共 19 条

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