Supramolecular polymers: From scientific curiosity to technological reality

被引：76

作者：

Bosman, AW

Brunsveld, L

Folmer, BJB

Sijbesma, RP

Meijer, EW

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

[2] SupraPolix Res Ctr, NL-5612 AX Eindhoven, Netherlands

来源：

MACROMOLECULAR SYMPOSIA | 2003年 / 201卷

关键词：

equilibrium polymers; hydrogen bonding; macromolecules; supramolecular polymers; ureidopyrimidinone units;

D O I：

10.1002/masy.200351117

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Supramolecular polymers([1]) are introduced as a new approach to come to materials in which the repeating units are not connected by covalent bonds but by specific secondary interactions. Self-complementary quadruple hydrogen bonded structures with high association constants are presented as easy to synthesize fragments in supramolecular polymers. Some of the many possibilities of equilibrium polymers are discussed, while it is shown that these supramolecular polymers can obtain materials properties normally only obtained with macromolecules.

引用

页码：143 / 154

页数：12

共 36 条

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