Synthesis and structure of the new complex hydride Li2BH4NH2

被引：44

作者：

Chater, Philip A.

David, William I. F.

Anderson, Paul A. ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

[2] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 45期

关键词：

D O I：

10.1039/b711111h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the new complex hydride Li2BH4NH2, determined through Rietveld analysis of synchrotron X-ray and neutron powder diffraction data, comprises a hexagonal array of discrete (LiNH2)(6) clusters dispersed in a LiBH4 matrix.

引用

页码：4770 / 4772

页数：3

共 20 条

[1]

[Anonymous], 2007, CRC HDB CHEM PHYS IN

[2] Destabilization of LiBH4 by mixing with LiNH2 [J].

Aoki, M ;

Miwa, K ;

Noritake, T ;

Kitahara, G ;

Nakamori, Y ;

Orimo, S ;

Towata, S .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2005, 80 (07) :1409-1412

[3] Synthesis and characterization of amide-borohydrides: New complex light hydrides for potential hydrogen storage [J].

Chater, Philip A. ;

Anderson, Paul A. ;

Prendergast, James W. ;

Walton, Allan ;

Mann, Vicky S. J. ;

Book, David ;

David, William I. F. ;

Johnson, Simon R. ;

Edwards, Peter P. .

JOURNAL OF ALLOYS AND COMPOUNDS, 2007, 446 :350-354

[4]

COELHO AA, 2004, TOPAS GEN PROFILE ST

[5] On the composition and crystal structure of the new quaternary hydride phase Li4BN3H10 [J].

Filinchuk, YE ;

Yvon, K ;

Meisner, GP ;

Pinkerton, FE ;

Balogh, MP .

INORGANIC CHEMISTRY, 2006, 45 (04) :1433-1435

[6]

Gillan R, 2006, CHEM WORLD-UK, V3, P26, DOI 10.1039/b518243c

[7] CRYSTAL STRUCTURE OF MAGNESIUM AMIDE [J].

JACOBS, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 382 (02) :97-&

[8] A TRI-LITHIUM SODIUM AMIDE, LI3NA(NH2)4, A COMPOUND WITH A STRUCTURE POSSESSING AN AFFINITY TO LITHIUM AMIDE [J].

JACOBS, H ;

HARBRECHT, B .

JOURNAL OF THE LESS-COMMON METALS, 1982, 85 (01) :87-95

[9] Decomposition of LiAl(NH2)4 and reaction with LiH for a possible reversible hydrogen storage [J].

Janot, Raphael ;

Eymery, Jean-Bruno ;

Tarascon, Jean-Marie .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (05) :2335-2340

[10]

Larson AC, 2000, 86748 LAUR

← 1 2 →