Crystal growth, structure determination and magnetism of a new hexagonal rhodate:: Ba9Rh8O24

被引：29

作者：

Stitzer, KE

Smith, MD

Darriet, J

zur Loye, HC ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

[2] CNRS, ICMCB, F-33608 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b104513j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of Ba9Rh8O24, grown from a molten potassium carbonate flux, crystallize in the spacegroup R (3) over barc with lattice parameters of a = 10.0899(4) and c = 41.462(2) Angstrom. Magnetic measurements on oriented single crystals reveal the existence of magnetic anisotropy.

引用

收藏

页码：1680 / 1681

页数：2

相关论文

共 12 条

[1] NICKEL SUPERMIXED VALENCE IN STOICHIOMETRIC BANI0.83O2.5 [J].

CAMPA, JA ;

GUTIERREZPUEBLA, E ;

MONGE, MA ;

RASINES, I ;

RUIZVALERO, C .

JOURNAL OF SOLID STATE CHEMISTRY, 1994, 108 (02) :230-235

[2] STRUCTURAL RELATIONSHIPS BETWEEN COMPOUNDS BASED ON THE STACKING OF MIXED LAYERS RELATED TO HEXAGONAL PEROVSKITE-TYPE STRUCTURES [J].

DARRIET, J ;

SUBRAMANIAN, MA .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (04) :543-552

[3]

DUSSARRAT C, 1995, EUR J SOL STATE INOR, V32, P3

[4] Crystal structure and possible charge ordering in one-dimensional Ca3Co2O6 [J].

Fjellvag, H ;

Gulbrandsen, E ;

Aasland, S ;

Olsen, A ;

Hauback, BC .

JOURNAL OF SOLID STATE CHEMISTRY, 1996, 124 (01) :190-194

[5] Single crystal study of the one dimensional Ca \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document}Co \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document}O \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}\end{document} compound: five stable configurations for the Ising triangular lattice [J].

A. Maignan ;

C. Michel ;

A.C. Masset ;

C. Martin ;

B. Raveau .

The European Physical Journal B - Condensed Matter and Complex Systems, 2000, 15 (4) :657-663

[6] Structure of composites A1+x (A′xB1-x)O3 related to the 2H hexagonal perovskite:: relation between composition and modulation [J].

Perez-Mato, JM ;

Zakhour-Nakhl, M ;

Weill, F ;

Darriet, J .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (11) :2795-2808

[7] THE CRYSTAL STRUCTURE OF SR4PTO6 AND 2 RELATED COMPOUNDS [J].

RANDALL, JJ ;

KATZ, L .

ACTA CRYSTALLOGRAPHICA, 1959, 12 (07) :519-521

[8] Sr3ARhO6 (A = Li, Na):: Crystallization of a rhodium(V) oxide from molten hydroxide [J].

Reisner, BA ;

Stacy, AM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (37) :9682-9683

[9]

STITZER KE, IN PRESS J AM CHEM S

[10] ON CA3IRCUO6 [J].

TOMASZEWSKA, A ;

MULLERBUSCHBAUM, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (03) :534-536