High Propene/Propane Selectivity in Isostructural Metal-Organic Frameworks with High Densities of Open Metal Sites

被引：411

作者：

Bae, Youn-Sang ^{[2
]}

Lee, Chang Yeon ^{[1
]}

Kim, Ki Chul ^{[2
]}

Farha, Omar K. ^{[1
]}

Nickias, Peter ^{[3
]}

Hupp, Joseph T. ^{[1
]}

Nguyen, SonBinh T. ^{[1
]}

Snurr, Randall Q. ^{[2
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA

[3] Dow Chem Co USA, Core R&D, Midland, MI 48674 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 08期

关键词：

adsorption; metal-organic frameworks; open metal sites; propane; propene; HYDROGEN STORAGE; CARBON-DIOXIDE; MOLECULAR SIMULATION; KINETIC SEPARATION; GAS-ADSORPTION; SURFACE-AREA; CO2; PROPANE; CH4; TEMPERATURE;

D O I：

10.1002/anie.201107534

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1857 / 1860

页数：4

共 52 条

[41] Metal-organic frameworks: a new class of porous materials
Rowsell, JLC
Yaghi, OM
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 73 (1-2) : 3 - 14
[42] Rowsell JLC, 2005, ANGEW CHEM, V117, P4748
[43] Understanding the Anomalous Alkane Selectivity of ZIF-7 in the Separation of Light Alkane/Alkene Mixtures
van den Bergh, Johan
Gucuyener, Canan
Pidko, Evgeny A.
Hensen, Emiel J. M.
Gascon, Jorge
Kapteijn, Freek
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (32) : 8832 - 8840
[44] Wang QM, 2002, MICROPOR MESOPOR MAT, V55, P217
[45] Xiang S, 2010, ANGEW CHEM, V49, P4719, DOI [10.1002/ange.201000094, DOI 10.1002/ANGE.201000094]
[46] Open Metal Sites within Isostructural Metal-Organic Frameworks for Differential Recognition of Acetylene and Extraordinarily High Acetylene Storage Capacity at Room Temperature
Xiang, Shengchang
Zhou, Wei
Zhang, Zhangjing
Green, Mark A.
Liu, Yun
Chen, Banglin
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (27) : 4615 - 4618
[47] High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework
Xiao, Bo
Wheatley, Paul S.
Zhao, Xuebo
Fletcher, Ashleigh J.
Fox, Sarah
Rossi, Adriano G.
Megson, Ian L.
Bordiga, S.
Regli, L.
Thomas, K. Mark
Morris, Russell E.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (05) : 1203 - 1209
[48] Molecular simulation of carbon dioxide/methane/hydrogen mixture adsorption in metal-organic frameworks
Yang, Qingyuan
Zhong, Chongli
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (36) : 17776 - 17783
[49] Yang RT, 2003, New construction of ternary locally repairable codes that are also LCD codes
[50] Screening of Metal-Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach
Yazaydin, A. Oezguer
Snurr, Randall Q.
Park, Tae-Hong
Koh, Kyoungmoo
Liu, Jian
LeVan, M. Douglas
Benin, Annabelle I.
Jakubczak, Paulina
Lanuza, Mary
Galloway, Douglas B.
Low, John J.
Willis, Richard R.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (51) : 18198 - +

← 1 2 3 4 5 6 →