The invention of radical reactions .37. A convenient radical synthesis of dialkyl diselenides from carboxylic acids.

被引：18

作者：

Barton, DHR

Fontana, G

机构：

[1] Department of Chemistry, Texas A and M University, College Station

来源：

TETRAHEDRON | 1996年 / 52卷 / 34期

关键词：

D O I：

10.1016/0040-4020(96)00665-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and convenient synthesis of dialkyl diselenides from carboxylic acids by Barton PTOC ester based radical chemistry is described. This method was especially successful when O-cholestan-3 beta-yl-2,2,2-tricholoroselenoacetate and O-neopentyl selenobenzoate were used as radical traps. Copyright (C) Elsevier Science Ltd

引用

页码：11163 / 11176

页数：14

共 55 条

[21]

CLIVE DL, 1978, J TETRAHEDRON, V34, P1048

[22] CONVERSION OF ALDEHYDES AND KETONES INTO SELENOACETALS - USE OF TRIS-(PHENYLSELENO)BORANE AND TRIS-(METHYLSELENO)BORANE [J].