Aerobic oxidation of a disulfide to its sulfonate leading to supramolecular pyridine-2-sulfonato Cu(II) and Zn(II) complexes

被引：40

作者：

Kimura, K ^{[1
]}

Kimura, T ^{[1
]}

Kinoshita, I ^{[1
]}

Nakashima, N ^{[1
]}

Kitano, K ^{[1
]}

Nishioka, T ^{[1
]}

Isobe, K ^{[1
]}

机构：

[1] Osaka City Univ, Grad Sch Sci, Dept Mol Mat Sci, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 06期

关键词：

D O I：

10.1039/a809513b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-dimensional copper(II) complex with pyridine-2-sulfonate donors, [{Cu(3-mpSO(3))(2)}(n)] (3-mpSO(3) = 3-methylpyridine-2-sulfonate), is formed via the air oxidation of 3-mpds (2,2'-bis(3-methylpyridyl)disulfide) in the presence of CuBr2, and a mononuclear zinc complex, [Zn(3-mpSO(3))(2)(H2O)(2)], which has two-dimensional H-bonded networks and luminescent properties in solid state, is prepared by the reaction of ZnBr2 with 3-mpSO(3)H.

引用

页码：497 / 498

页数：2

共 15 条

[1] THE EFFECT OF LIGAND VARIATION ON THE RATE OF CYCLODODECANE OXIDATION UNDER MODIFIED GO AGG-2 CONDITIONS [J].

ABOUTJAUDET, E ;

BARTON, DHR ;

CSUHAI, E ;

OZBALIK, N .

TETRAHEDRON LETTERS, 1990, 31 (12) :1657-1660

[2]

CHARBONNIER F, 1981, CRYST STRUCT COMMUN, V10, P1129

[3] PYRIDINE-4-SULPHONIC ACID [J].

COMRIE, AM ;

STENLAKE, JB .

JOURNAL OF THE CHEMICAL SOCIETY, 1958, (MAY) :1853-1854

[4] CHEMISTRY OF SMALL-RING SULFUR COMPOUNDS - THIETANES AND 1,2-DITHIOLANES [J].

HARPP, DN ;

GLEASON, JG .

JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (10) :3259-&

[5] A unique mononuclear nickel disulfonato complex obtained by oxidation of a mononuclear nickel dithiolate complex [J].

Henderson, RK ;

Bouwman, E ;

Spek, AL ;

Reedijk, J .

INORGANIC CHEMISTRY, 1997, 36 (21) :4616-4617

[6] CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(2-PYRIDINE SULFINATO)COPPER(II) [J].

HIGASHI, LS ;

LUNDEEN, M ;

HILTI, E ;

SEFF, K .

INORGANIC CHEMISTRY, 1977, 16 (02) :310-313

[7]

HORNING EC, 1955, ORG SYNTH, V3, P136

[8] CHLORINATION OF BIS(ETHYLENEDIAMINE)COBALT(III) COMPLEXES CONTAINING CHELATED N,S-BOUND (R)-CYSTEINE AND CYSTEAMINE - NOVEL OXIDATIVE RING EXPANSION REACTIONS [J].

JACKSON, WG ;

SARGESON, AM .

INORGANIC CHEMISTRY, 1988, 27 (06) :1068-1073

[9]

KALLISTRATOS G, 1982, CHEM CHRON, V11, P249

[10]

Lehn J.-M., 1995, SUPRAMOL CHEM, P89

← 1 2 →