Palladium-catalyzed reaction of 1-aza-5-germa-5-organobicyclo[3.3.3]undecane with aryl bromide

被引：49

作者：

Kosugi, M

Tanji, T

Tanaka, Y

Yoshida, A

Fugami, K

Kameyama, K

Migita, T

机构：

[1] OYAMA NATL COLL TECHNOL,OYAMA,TOCHIGI 323,JAPAN

[2] TOKAI UNIV,SCH HIGH TECHNOL HUMAN WELF,NUMAZU,SHIZUOKA 41003,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 508卷 / 1-2期

关键词：

germanium; cross-coupling; palladium; catalysis;

D O I：

10.1016/0022-328X(95)05840-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Successive treatment of triallylamine with zirconocene chloride hydride and germanium tetrachloride affords 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane, which is converted to the 5-organo derivatives by the reaction with Grignard or lithium reagents. The organo groups showed higher reactivities toward Stille-type coupling than the corresponding organotributylgermanes.

引用

页码：255 / 257

页数：3

共 16 条

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