Stereoselective synthesis of cyclopentanols by Lewis acid-mediated [3+2] annulation of allyldiisopropylphenylsilane with α,β-unsaturated diesters

被引：32

作者：

Akiyama, T ^{[1
]}

Yamanaka, M ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 43期

关键词：

annulation; cyclobutanes; cyclopentanes; silicon and compounds;

D O I：

10.1016/S0040-4039(98)01748-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ZrCl4-mediated annulation of allyldiisopropylphenylsilane with alpha,beta-unsaturated diesters and subsequent oxidative cleavage of the carbon-silicon bond furnished cyclopentanols highly stereoselectively. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7885 / 7888

页数：4

共 37 条

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[9] 5-MEMBERED RING ANNULATION VIA PROPARGYLSILANES AND ALLYLSILANES
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