LiAlH4 promoted reductive deoxygenation of hydroxybenzyl alcohols via benzoquinone methide intermediates.

被引：20

作者：

Baik, W ^{[1
]}

Lee, HJ

Koo, S

Kim, BH

机构：

[1] Myong Ji Univ, Dept Chem, Yong In 449728, Kyung Ki Do, South Korea

[2] Kwangwoon Univ, Dept Chem, Seoul, South Korea

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(98)01803-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Primary and secondary hydroxybenzyl alcohols react with LiAlH4 in chlorobenzene to give the corresponding alkylphenols. The reaction proceeds through the formation of benzoquinone methide as an intermediate. An example of [4+2] cycloaddition of benzoquinone methide is also reported. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：8125 / 8128

页数：4

共 16 条

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