Formation of metallaboratranes:: The missing link.: The first iridaboratranes, [IrH(CO)(PPh3){κ3-B,S,S′-B(mt)2R}](Ir→B) (mt = methimazolyl, R = mt, H)

被引：113

作者：

Crossley, IR ^{[1
]}

Hill, AF ^{[1
]}

Willis, AC ^{[1
]}

机构：

[1] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 06期

关键词：

D O I：

10.1021/om040128f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Vaska's complex with 1 equiv of Na[HB(mt)(3)] or Na[H2B(mt)(2)] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){kappa(3)-B,S,S'-B(mt(2))R}](Ir-I -> B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal -> boron bond is supported by only two methimazolyl buttresses.

引用

页码：1062 / 1064

页数：3