Chemical stability study of Li2SO4 on the operation condition of a H2/O2 fuel cell

被引：21

作者：

Tao, SW ^{[1
]}

Zhan, ZL ^{[1
]}

Wang, P ^{[1
]}

Meng, GY ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China

来源：

SOLID STATE IONICS | 1999年 / 116卷 / 1-2期

关键词：

Li2SO4; chemical stability; fuel cell; proton conductor;

D O I：

10.1016/S0167-2738(98)00263-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chemical stability of Li2SO4 on the operation condition of a H-2/O-2 fuel cell has been investigated in this work. Thermodynamic calculation indicates Li2SO4 can react with H-2 at high temperature. The H-2/O-2 fuel cell using Li2SO4-alpha-Al2O3 as electrolyte exhibits good performance, but the stability of performance is not good. XRD analysis indicates that Li2SO4 reacts with H-2 at high temperature. Therefore, the Li2SO4-based proton conductors are not suitable for electrolytes for H-2/O-2 fuel cells. (C) 1999 Published by Elsevier Science B.V. All rights reserved.

引用

页码：29 / 33

页数：5

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