2-biphenylenylcarbene

被引：5

作者：

Wu, GX

Jones, M ^{[1
]}

Walton, R

Lahti, PM

机构：

[1] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

[2] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 16期

关键词：

D O I：

10.1021/jo980169j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactivity and EPR spectroscopy of 2-biphenylenylcarbene have been examined. The reactive spin state is the singlet. The zero-field splitting parameters for the ground-state triplet approximate those of phenylcarbene.

引用

页码：5368 / 5371

页数：4

共 24 条

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[22] ELECTRONIC SPECTROSCOPY OF ARYLMETHYLENES
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[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1968, 1 (11) : 329 - &
[23] TROZZOLO AM, 1965, J AM CHEM SOC, V87, P129
[24] Wentrup C., 1989, METHODEN ORG CHEM E, VE19b, P824

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